陕西黑河流域地下水水化学特征     

王晓艳 《中国沙漠》2019,39(4):168-176

2017年在秦岭黑河流域7个采样点进行地下水样品采集。通过综合分析、Gibbs图、Piper三角图、主要离子比值法、主成分分析法得出黑河地下水化学成分的特点、水化学类型及其成因。结果表明：阳离子的主要组成成分是Ca²⁺，HCO₃^-是阴离子的主要组成成分，黑河流域地下水化学类型为HCO₃^-- Ca²⁺和SO₄^2--HCO₃^--Ca²⁺型。Gibbs图分析得出该地下水化学离子组成受岩石风化作用控制；Piper三角图、主要离子比值法、主成分分析及相关分析表明，地下水化学组分主要受方解石、白云岩等碳酸盐岩矿物的风化溶解，同时伴有硫酸溶解碳酸盐岩，受硅酸盐岩的溶解控制作用较小。  相似文献   

Flexural deformation controls on Late Quaternary sediment dispersal in the Garo-Rajmahal Gap,NW Bengal Basin     

Jean-Louis Grimaud  Celine Grall  Steven Goodbred  Michael S. Steckler  Ryan Sincavage  Jennifer L. Pickering  Chris Paola  Leonardo Seeber  Md. Saddam Hossain 《Basin Research》2020,32(5):1242-1260

Subsurface deformation is a driver for river path selection when deformation rates become comparable to the autogenic mobility rate of rivers. Here we combine geomorphology, soil and sediment facies analyses, and geophysical data of the Late Quaternary sediments of the central Garo-Rajmahal Gap in Northwest Bengal to link subsurface deformation with surface processes. We show variable sedimentation characteristics, from slow rates (<0.8 mm/year) in the Tista megafan at the foot of the Himalaya to nondeposition at the exposed surface of the Barind Tract to the south, enabling the development of mature soils. Combined subsidence in the Tista fan and uplift of the Barind Tract are consistent with a N-S flexural response of the Indian plate to loading of the Himalaya Mountains given a low value of elastic thickness (15–25 km). Provenance analysis based on bulk strontium concentration suggests a dispersal of sediment consistent with this flexural deformation—in particular the abandonment of the Barind Tract by a Pleistocene Brahmaputra River and the current extents of the Tista megafan lobes. Overall, these results highlight the control by deeply rooted deformation patterns on the routing of sediment by large rivers in foreland settings.  相似文献   

晋西北地区表层土壤粒度与地球化学元素组成   总被引：1，自引：1，他引：0  

李继彦  周玲  刘益  张倩  蔡莹莹  张宝贵 《中国沙漠》2019,39(5):155-162

对晋西北地区表层土壤的物质组成进行研究，可以明确其物质来源、沉积环境及化学风化特征。选择区内表层土壤（深度0、10、20 cm）及其附近的河流沉积物，进行粒度和化学元素组成测试。结果表明：（1）晋西北地区表层土壤粒度组成以黏土和粉沙为主，且有自地表向下粗颗粒组分含量增加的趋势。（2）常量化学元素组成以SiO₂、Al₂O₃、CaO、Fe₂O₃为主，其余元素含量均较低。化学元素组成模式表明研究区内表层土壤物质与黄土高原腹地黄土有相同的物质源区，黄河河流沉积物对其贡献不大。（3）晋西北表层土壤的CIA值为52.70~57.89，平均54.06，说明它们的化学风化程度较低，处于早期的脱Na、Ca阶段。这是由于研究区地理位置比洛川更靠北，气温和降水量均低于洛川，降水量与兰州相差不大，但是年平均气温和年温差比兰州低。该研究明确了晋西北地区表层土壤的物质组成特征，为区域潜在沙漠化危害防治提供了数据支撑。  相似文献   

Insights into agricultural influences and weathering processes from major ion patterns          下载免费PDF全文

Robert van Geldern  Peter Schulte  Michael Mader  Alfons Baier  Johannes A.C. Barth  Tobias R. Juhlke  Kern Lee 《水文研究》2018,32(7):891-903

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.  相似文献   

入园率视角下长三角地区化工产业时空格局演化及影响因素     

纪学朋  宋娅娅  孙延伟  王丹阳  孟浩  李升峰  黄贤金 《地理研究》2020,39(5):1116-1127

本文以全国化工产业密集区——长三角地区为例,基于规模以上中国工业企业详细数据,从化工企业入园率的视角出发,综合运用均值中心、标准差椭圆、核密度分析及空间自相关等分析方法,分析并揭示了1998—2013年长三角地区化工产业时空格局演化规律及影响因素。研究结果表明：1998—2013年长三角地区化工企业总体上呈现不断增长趋势,入园率由6.19%提升到36.98%;化工企业“西北-东南”方向分布明显,且近似呈“先东南,后西北”的路径迁移规律,较之全部企业,入园企业具有更高的离散度、更大的迁移幅度,入园企业与全部企业逐步由空间失配演变为空间匹配;中心集聚与外围扩散态势并存,发育并逐渐形成了环太湖集聚区、沿杭州湾集聚区、沿长江密集带及沿海密集带四大化工产业集聚片区,化工产业的区域空间结构趋于复杂化、有序化与稳定化;地级尺度上化工企业入园率不断提升,2003年与2013年呈显著的空间正相关,热点区逐渐由浙江东南转移到苏皖北部,冷点区从安徽北部迁移到浙江西北,基本完成了空间格局上的对称反转变换,但化工企业入园率与空间密度分布一直处于错配失衡状态。通过结合化工产业特性与长三角区域特征,定性探讨了长三角地区化工产业时空格局演化的影响因素,特别是阐述了化工产业“园区化”进程的作用机制。  相似文献   

Near‐surface hydraulic conductivity of northern hemisphere glaciers          下载免费PDF全文

Ian T. Stevens  Tristram D.L. Irvine‐Fynn  Philip R. Porter  Joseph M. Cook  Arwyn Edwards  Martin Smart  Brian J. Moorman  Andy J. Hodson  Andrew C. Mitchell 《水文研究》2018,32(7):850-865

The hydrology of near‐surface glacier ice remains a neglected aspect of glacier hydrology despite its role in modulating meltwater delivery to downstream environments. To elucidate the hydrological characteristics of this near‐surface glacial weathering crust, we describe the design and operation of a capacitance‐based piezometer that enables rapid, economical deployment across multiple sites and provides an accurate, high‐resolution record of near‐surface water‐level fluctuations. Piezometers were employed at 10 northern hemisphere glaciers, and through the application of standard bail–recharge techniques, we derive hydraulic conductivity (K) values from 0.003 to 3.519 m day^?1, with a mean of 0.185 ± 0.019 m day^?1. These results are comparable to those obtained in other discrete studies of glacier near‐surface ice, and for firn, and indicate that the weathering crust represents a hydrologically inefficient aquifer. Hydraulic conductivity correlated positively with water table height but negatively with altitude and cumulative short‐wave radiation since the last synoptic period of either negative air temperatures or turbulent energy flux dominance. The large range of K observed suggests complex interactions between meteorological influences and differences arising from variability in ice structure and crystallography. Our data demonstrate a greater complexity of near‐surface ice hydrology than hitherto appreciated and support the notion that the weathering crust can regulate the supraglacial discharge response to melt production. The conductivities reported here, coupled with typical supraglacial channel spacing, suggest that meltwater can be retained within the weathering crust for at least several days. Not only does this have implications for the accuracy of predictive meltwater run‐off models, but we also argue for biogeochemical processes and transfers that are strongly conditioned by water residence time and the efficacy of the cascade of sediments, impurities, microbes, and nutrients to downstream ecosystems. Because continued atmospheric warming will incur rising snowline elevations and glacier thinning, the supraglacial hydrological system may assume greater importance in many mountainous regions, and consequently, detailing weathering crust hydraulics represents a research priority because the flow path it represents remains poorly constrained.  相似文献   

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

化学刺激法提高花岗岩类岩石裂隙渗透性的实验研究     

郭清海  何曈  庄亚芹  骆进  张灿海 《地学前缘》2020,27(1):159-169

增强型地热系统(EGS)用于通过人工形成地热储层的方法从深部低渗透性岩体中开采地热能;国际上常采用水力压裂辅以化学刺激的方法改造EGS 储层以提高其渗透率。本文以采自青海共和盆地的花岗闪长岩样品为对象,选用3种不同化学刺激剂(氢氧化钠、盐酸和土酸),在3组不同注入流速条件下开展了系统化学刺激实验。结果表明:注入盐酸和土酸后样品渗透率均有提高,且采用土酸时渗透率提高幅度明显大于盐酸;但注入氢氧化钠后,样品渗透率反而降低。在3类化学刺激剂中,土酸对长石类矿物的溶蚀能力最强,而氢氧化钠溶液对石英的溶蚀能力最强,但氢氧化钠溶液在溶解岩石样品裂隙表面矿物后极易形成非定形态二氧化硅或非定形态铝硅酸盐蚀变矿物并阻塞裂隙,反而对化学刺激效果造成负面影响。总体来看,土酸是青海共和盆地干热岩体的最佳化学刺激剂。在中等注入速度(3 mL·min^-1)条件下,土酸对岩石样品的溶蚀程度就可达到最高;在此基础上进一步降低流速,则可能使溶解组分更易从液相中沉淀而充填于样品裂隙,导致样品渗透率有所下降。  相似文献   

早渐新世钙质超微化石演变与营养盐及二氧化碳关系     

马瑞罡  杨海长  金晓波  赵钊  张功成  刘传联 《海洋学报(英文版)》2020,39(10):70-80

南海北部早渐新世发生明显的营养供给和二氧化碳浓度的变化，相关地质记录为研究颗石藻的生理机制提供了理想的自然实验室。在本研究中，我们建立了一个新的颗石藻群落演化的指标，定义为E*比值。该比值由富营养属种和中等-贫营养属种的相对丰度计算而得（E^*=e/(e+c)×100，e代表富营养属种，c代表中等-贫营养属种）。其中富营养属种包括小Reticulofenestra， Reticulofenestra lockeri组，Reticulofenestra bisecta组和Coccolithus pelagicus组，而中等-贫营养属种包括Cyclicargolithus spp.。E^*指标与早渐新世营养盐指标具有较强的相关性，但在不同二氧化碳浓度的条件下表现不同的公变趋势。将群落组合与已发表的二氧化碳浓度数据对比，我们提出颗石藻可能在二氧化碳持续降低的环境下改变其对碳源和营养盐的利用方式，指示颗石藻的碳浓缩机制可能开始于早渐新世。  相似文献   

Climate driven coevolution of weathering profiles and hillslope topography generates dramatic differences in critical zone architecture     

Robert S. Anderson  Harihar Rajaram  Suzanne P. Anderson 《水文研究》2019,33(1):4-19

Considerable debate revolves around the relative importance of rock type, tectonics, and climate in creating the architecture of the critical zone. We demonstrate the importance of climate and in particular the rate of water recharge to the subsurface, using numerical models that incorporate hydrologic flowpaths, chemical weathering, and geomorphic rules for soil production and transport. We track alterations in both solid phase (plagioclase to clay) and water chemistry along hydrologic flowpaths that include lateral flow beneath the water table. To isolate the role of recharge, we simulate dry and wet cases and prescribe identical landscape evolution rules. The weathering patterns that develop differ dramatically beneath the resulting parabolic interfluves. In the dry case, incomplete weathering is shallow and surface parallel, whereas in the wet case, intense weathering occurs to depths approximating the base of the bounding channels, well below the water table. Exploration of intermediate cases reveals that the weathering state of the subsurface is strongly governed by the ratio of the rate of advance of the weathering front itself controlled by the water input rate, and the rate of erosion of the landscape. The system transitions between these end‐member behaviours rather abruptly at a weathering front speed ‐ erosion rate ratio of approximately 1. Although there are undoubtedly direct roles for tectonics and rock type in critical zone architecture, and yet more likely feedbacks between these and climate, we show here that differences in hillslope‐scale weathering patterns can be strongly controlled by climate.  相似文献